|
|||||
|
|
Highly efficient RuCl3-catalyzed disproportionation of (diacetoxyiodo)benzene to iodylbenzene and iodobenzene; leading to the efficient oxidation of alcohols to carbonyl compounds |
|
| Authors: | Mekhman S Yusubov Joo Yeon Park Viktor V Zhdankin |
| Institution: | a The Siberian State Medical University, 2 Moskovsky trakt, 634050 Tomsk, Russia and The Tomsk Polytechnic University, 30 Lenin st., 634050 Tomsk, Russia b University of Ulsan, 680-749 Ulsan, Republic of Korea c Department of Chemistry and Biochemistry, University of Minnesota Duluth, Duluth, Minnesota 55812, USA |
| Abstract: | (Diacetoxyiodo)benzene (DIB) selectively oxidizes primary and secondary alcohols to the respective carbonyl compounds in the presence of RuCl3 (0.8-1.0 mol %) at room temperature in aqueous acetonitrile. This reaction proceeds via an initial instantaneous Ru-catalyzed disproportionation of DIB to iodobenzene and iodylbenzene with the latter acting as the actual stoichiometric oxidant toward alcohols. |
| Keywords: | Hypervalent iodine (Diacetoxyiodo)benzene Iodylbenzene Oxidation Catalysis |
| 本文献已被 ScienceDirect 等数据库收录！ | |