Sinularianins A and B, novel sesquiterpenoids from the Formosan soft coral Sinularia sp. |
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Authors: | Chih-Hua Chao Shin-Pin Chen Chang-Feng Dai |
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Affiliation: | a Department of Marine Biotechnology and Resources, National Sun Yat-sen University, Kaohsiung 804, Taiwan, ROC b National Museum of Marine Biology and Aquarium, Checheng, Pingtung 944, Taiwan, ROC c Institute of Marine Biotechnology, National Dong Hwa University, Checheng, Pingtung 944, Taiwan, ROC d Institute of Oceanography, National Taiwan University, Taipei 106, Taiwan, ROC |
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Abstract: | Two novel sesquiterpenoids, sinularianins A and B (1 and 2), have been isolated from the Formosan coral Sinularia sp. The skeleton of sinularianins A (1), namely sinulariolane, was found to be unprecedented. Sinularianin B (2), with a novel spiro-butenolide moiety, possesses a valerenane skeleton, which had been reported mostly from the plant. The structures of both metabolites were established by extensive analysis of spectroscopic data. |
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Keywords: | Sinularianin A Sinularianin B Sinularia sp. Novel sesquiterpene Soft coral |
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