BODIPY appended cone-calix[4]arene: selective fluorescence changes upon Ca binding |
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| Authors: | Hyun Jung Kim |
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| Institution: | Department of Chemistry, Institute of Nanosensor and Biotechnology, Dankook University, Seoul 140-714, Republic of Korea |
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| Abstract: | BODIPY appended new calix4]arene diethyl ester (1) has been synthesized in the cone conformation. With respect to fluorescence intensity changes upon metal ion complexation, 1 shows a Ca2+ ion selectivity over other metal cations. Presence of two proximal hydroxyl groups and two facing ethyl esters in BODIPY-calix4]arene were observed to play an important role in exhibiting its selective Ca2+ ion binding. |
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| Keywords: | Calixarenes Fluorescence Reverse PET |
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