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Studies toward the total synthesis of tedanolide: stereoselective synthesis of the C(8)-C(17) segment
Authors:Vijay Kumar Nyavanandi  Srinivas Nanduri  Andra Naidu
Affiliation:a Discovery Chemistry, Discovery Research, Dr. Reddy’s Laboratories Ltd., Miyapur, Hyderabad 500049, India
b Analytical Research, Discovery Research, Dr. Reddy’s Laboratories Ltd., Miyapur, Hyderabad 500049, India
c Jawaharlal Nehru Technological University, Kukatpally, Hyderabad 500072, India
Abstract:The stereoselective synthesis of the C(8)-C(17) sub-unit (−)-5 of tedanolide (1), which involves iterative Evans aldol reactions as the key steps, is described.
Keywords:Tedanolide   Stereoselective   Aldol   Boron reagent
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