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Studies toward the total synthesis of tedanolide: stereoselective synthesis of the C(8)-C(17) segment |
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| Authors: | Vijay Kumar Nyavanandi Srinivas Nanduri Andra Naidu |
| Institution: | a Discovery Chemistry, Discovery Research, Dr. Reddy’s Laboratories Ltd., Miyapur, Hyderabad 500049, India b Analytical Research, Discovery Research, Dr. Reddy’s Laboratories Ltd., Miyapur, Hyderabad 500049, India c Jawaharlal Nehru Technological University, Kukatpally, Hyderabad 500072, India |
| Abstract: | The stereoselective synthesis of the C(8)-C(17) sub-unit (−)-5 of tedanolide (1), which involves iterative Evans aldol reactions as the key steps, is described. |
| Keywords: | Tedanolide Stereoselective Aldol Boron reagent |
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