Microwave-enhanced cross-coupling of allyl chlorides with vinyltrifluoroborates |
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Authors: | George W Kabalka Eric Dadush |
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Institution: | a Departments of Chemistry and Radiology, The University of Tennessee, Knoxville, TN 37996-1600, USA b Department of Chemistry, Tennessee State University, Nashville, TN 37209, USA |
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Abstract: | The allylation of potassium alkenyltrifluoroborates with allyl chloride via a palladium catalyzed cross-coupling reaction occurs rapidly under microwave irradiation. The allylation reaction produces 1,4-pentadienes in high yields. |
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