CRYSTAL AND MOLECULAR STRUCTURE OF N—ETHYLPHENOTHIAZINE RADICAL CATION HEXACHLOROANTIMONATE EPT^+SbCl6^— |
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引用本文: | 刘有成,王奇光,等.CRYSTAL AND MOLECULAR STRUCTURE OF N—ETHYLPHENOTHIAZINE RADICAL CATION HEXACHLOROANTIMONATE EPT^+SbCl6^—[J].结构化学,1989,8(2):140-144. |
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作者姓名: | 刘有成 王奇光 等 |
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摘 要: | <正> C14H13Cl6NSSb, Mr =561.8, Monoclinic, C2/c1 8=15,32(1), b= 11.72(1), c= 11.10(1)A,β=99.31(3)°,V=1969(1)A3,Dc=1,902g.cm-3, Z=4,CuKα,λ=1.5418A,μ=200.95cm-1.Room temperature, final R=0.051 for 1197 unique reflections with I>, 3.0σ(I).Pronounced defornation of the Molecular structure has been observed when the neutral N-ethylphenothia-zine is transformed into its radical cation. The structural features of the radical cation are compared with those of N-methyl analogue.
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关 键 词: | 晶体结构 分子结构 锑配合物 N-乙基吩噻嗪 |
CRYSTAL AND MOLECULAR STRUCTURE OF N-ETHYLPHENOTHIAZINE RADICAL CATION HEXACHLOROANTIMONATE EPT+SbCl_6~- |
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Abstract: | C14H13Cl6NSSb, Mr =561.8, Monoclinic, C2/c1 8=15,32(1), b= 11.72(1), c= 11.10(1)A,β=99.31(3)°,V=1969(1)A3,Dc=1,902g.cm-3, Z=4,CuKα,λ=1.5418A,μ=200.95cm-1.Room temperature, final R=0.051 for 1197 unique reflections with I>, 3.0σ(I).Pronounced defornation of the Molecular structure has been observed when the neutral N-ethylphenothia-zine is transformed into its radical cation. The structural features of the radical cation are compared with those of N-methyl analogue. |
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