Hydrodynamic and conformational properties of cellulose myristate molecules in solution

Cellulose myristate samples with a degree of substitution of 230–250 have been studied by the methods of molecular hydrodynamics (viscometry, analytical ultracentrifugation (flotation), and isothermal translational diffusion) in chloroform in the range M = (56–652) × 10³. The experimental evidence has been interpreted within the framework of the generalized wormlike Yamakawa-Fuji model with the following parameters: the persistence length a = 115 × 10^?8 cm, the chain diameter d = 45 × 10^?8 cm, and the molecular mass per unit chain length M _L = 270 × 10⁸ cm^?1. It has been inferred that the polymer dissolves in chloroform in the form of dimers.