Microscopic approach to the pseudo-spin-1/2 Hamiltonian for Kramers doublets in exchange coupled Co(II) pairs |
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Authors: | Palii Andrei V Tsukerblat Boris S Coronado Eugenio Clemente-Juan Juan M Borrás-Almenar Juan J |
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Institution: | Instituto de Ciencia Molecular, Universidad de Valencia, C/Dr. Moliner 50, 46100-Burjassot (Valencia), Spain. |
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Abstract: | The microscopic theory of the magnetically anisotropic effective pseudo-spin-(1)/(2) Hamiltonian for a pair of Co(2+) ions is reported. In the framework of the second-order perturbation approach, the analytical expressions are found for the components of the tensor of the exchange interaction, g-tensor, and the factor in the temperature independent paramagnetic contribution. The parameters of the Hamiltonian are expressed in terms of the basic intra- and intercenter parameters of the pair, namely, the spin-orbit coupling constant, orbital reduction factor, exchange integral, and low symmetry crystal field parameters including axial and rhombic terms. |
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