Transition metal derivatives of 1,1′-dichloroferrocene |
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| Authors: | AG Osborne EH Whiteley |
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| Institution: | Department of Chemistry, University of Exeter, Exeter, U.K. |
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| Abstract: | Complexes of the general formula Cl2Fc] nML, (Cl2Fc = C1C5H4FeC5H3Cl; ML = Fe(CO)2C5H5, AuP(C6H5)3, Mn(CO)5 or Ir(CO)P(C6H5)3]2 when n = 1; ML = Ti(C5H5)2 when n = 2) have been prepared from a salt elimination reaction between 1,1′-dichloro-2-lithioferrocene and transition metal halide complexes. Spectroscopic properties of the compounds are reported. The titanium complex exists in meso and dl forms. |
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