Olefin-alkyl group exchange of B-alkyl-9-borabicyclo-[3.3.1]nonanes. Evidence for a dehydroboration-hydroboration process |
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| Authors: | M. Mark Midland Janet E. Petre Stephen A. Zderic |
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| Affiliation: | Department of Chemistry, University of California, Riverside, California 92521 U.S.A. |
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| Abstract: | B-Alkyl-9-borabicyclo[3.3.1]nonanes (9-BBN) undergo a rather facile olefin-alkyl group exchange process when refluxed with an olefin in tetrahydrofuran. Kinetic and competition studies support a dehydroboration-hydroboration process. |
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