Some reactions of copper(I) pentafluorothiophenolate as a nucleophile |
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Authors: | Linda J. Johnson Michael E. Peach |
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Affiliation: | Chemistry Department, Acadia University, Wolfville, Nova Scotia, BOP 1XO Canada |
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Abstract: | Several aromatic compounds containing one or two C6F5S groups have been prepared by nucleophilic displacement reactions using CuSC6F5 in DMF solution. Aromatic iodine or bromine, rather than chlorine of fluorine is replaced by the SC6F5 group using CuSC6F5. A mechanism is postulated. New compounds prepared include -(C6F6F5S)2C6H4, - and -(C6F5S)2C6F4 and XC6H4SC6F5(X=C1, NO2, I, CH3, CO2C2H5). |
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