19F and 31P NMR characterisation of the phosphaalkene,CF3 P=CF2, intermediate in the alkaline hydrolysis of bis(trifluoromethyl)phospine |
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Authors: | Hossein Eshtiagh-Hosseini Harold W. Kroto John F. Nixon Osamu Ohashi |
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Affiliation: | School of Molecular Sciences, University of Sussex, Brighton BN1 9QJ Great Britain |
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Abstract: | The previously postulated phosphaalkene intermediate CF3 P=CF2 in the alkaline hydrolyses of (CF3)2 PH has been trapped and characterised by its 19F and 31P NMR spectra. |
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