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19F and 31P NMR characterisation of the phosphaalkene,CF3 P=CF2, intermediate in the alkaline hydrolysis of bis(trifluoromethyl)phospine
Authors:Hossein Eshtiagh-Hosseini  Harold W. Kroto  John F. Nixon  Osamu Ohashi
Affiliation:School of Molecular Sciences, University of Sussex, Brighton BN1 9QJ Great Britain
Abstract:The previously postulated phosphaalkene intermediate CF3 P=CF2 in the alkaline hydrolyses of (CF3)2 PH has been trapped and characterised by its 19F and 31P NMR spectra.
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