Metal formyl complexes. The reaction of sodium pentacarbonylmanganate with acetic[13C]formic anhydride期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Metal formyl complexes. The reaction of sodium pentacarbonylmanganate with acetic[13C]formic anhydride

Authors:	RA Fiato JL Vidal RL Pruett

Institution:	Union Carbide Corporation, Chemicals and Plastics Division, So. Charleston, W.Va. 25303 U.S.A.

Abstract:	The reaction of acetic ¹³C]formic anhydride with sodiumpentacarbonylmanganate proceeds rapidly at 0°C to give ¹³CO substituted pentacarbonylmanganese hydride as the predominant product. The results are consistent with the formation of a short-lived neutral formyl complex, (CO)₅Mn¹³CHO.

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