Synthesis and crystal structure of [(Ph3P)2N] [Ni2(CO)6H] |
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| Authors: | Giuliano Longoni Mario Manassero Mirella Sansoni |
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| Affiliation: | 1. Centro del CNR per lo studio della sintesi e della struttufa dei composti dei metalli di transizione, via Venezian 21, 20133 Milano Italy;2. lstituto di Chimica Generale dell''Universitá di Milano, via Venezian 21, 20133 Milano Italy |
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| Abstract: | The interstitial dihydride dianion [Ni12(CO)21H2]2? is readily converted by carbon monoxide (25°C, 1 atm) into a mixture of tetracarbonylnickel and a new colourless hydride carbonyl monoanion, which has been characterized by X-ray diffraction as [Ni2(CO)6H]?. |
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