The direct electrochemical synthesis of anionic organodihalocadmate(II) complexes |
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| Authors: | Akhtar Osman Dennis G. Tuck |
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| Affiliation: | Department of Chemistry, University of Windsor, Windsor, Ontario N9B 3P4 Canada |
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| Abstract: | The tetra-n-propylammonium salts of RCdX2? anions (R = CH3, C2H5, C4H9, CF3, C6H5, C6F5; X = Cl, Br, I) have been prepared by the electrochemical oxidation of cadmium metal. The element forms the sacrificial anode of a cell in which the solution phase is a methanol/benzene mixture containing (C3H7)4NX and RX. Gram quantities of product were obtained by room temperature electrolysis for ca. 5 h. |
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