Radical ions : XXVI. Radical anions of perphenylcyclopolysilanes |
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| Authors: | Mitsuo Kira Hans Bock Edwin Hengge |
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| Institution: | Institute of Inorganic Chemistry, University of Frankfurt, Niederurseler Hang, D-6000 Frankfurt/Main 50 F.R.G.;Technical University of Graz, Stremayrgasse 16, A-8010 Graz Austria |
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| Abstract: | Perphenylcyclopolysilanes Si(C6H5)2]n (n = 4, 5) are reduced by potassium to radical anions. Their simple ESR spectra demonstrate, that the extra electron is confined to the inner SinC2n skeleton of the uncleaved and presumably planarized cyclopolysilanes. |
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