Isocyanide insertion into platinumoxygen bonds期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Isocyanide insertion into platinumoxygen bonds

Authors:	Rino A. Michelin Renzo Ros

Affiliation:	Centro di Chimica e Technologia dei Composti Metallorganici degli Elementi di Transizione del C.N.R., c/o Istituto di Chimica Industriale, Via F. Marzolo, 9, Padova Italy;Facoltà di Chimica Industriale, Università di Venezia, Venezia Calle Larga - S. Marta 2137 Italy

Abstract:	The reaction of isocyanides, CNR, with hydroxy- and methoxy-alkyl complexes of platinum(II), PtOH(R)(Ph₂ PCHCHPPh₂)_and PtOCH₃(R)(Ph₂PCHCHPPh₂) (R  CF₃, CH₂ CN) affords insertion products Pt(CONHR)(R)(Ph₂PCHCHPPh₂) and Pt[C(OCH₃)NR] (R)(Ph₂PCHCHPPh₂) containing the carboxamido and imidoyl moiety, respectively.

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