Phase-transfer catalysis in the nickel-catalyzed cyanation of aryl halides |
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Authors: | L. Cassar M. Foà F. Montanari G.P. Marinelli |
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Affiliation: | Istituto G. Donegani, Montedison, Via Fauser 4, 28100 Novara Italy;Istituto di Chimica Industriale, Università di Milano, Via Golgi 19, 20133 Milano Italy |
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Abstract: | The nickel-catalyzed cyanation of aromatic halides under phase-transfer conditions is reported. Both liquid—liquid and solid—liquid techniques have been used, the former giving better yields and a higher catalyst turnover. The method provides a convenient and versatile route to aromatic nitriles. |
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