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Phase-transfer catalysis in the nickel-catalyzed cyanation of aryl halides
Authors:L. Cassar  M. Foà  F. Montanari  G.P. Marinelli
Affiliation:Istituto G. Donegani, Montedison, Via Fauser 4, 28100 Novara Italy;Istituto di Chimica Industriale, Università di Milano, Via Golgi 19, 20133 Milano Italy
Abstract:The nickel-catalyzed cyanation of aromatic halides under phase-transfer conditions is reported. Both liquid—liquid and solid—liquid techniques have been used, the former giving better yields and a higher catalyst turnover. The method provides a convenient and versatile route to aromatic nitriles.
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