A 13C and 31P N.M.R. Investigation of restricted rotation in [Pt(η3-allyl){P(cyclohexyl)3}2]+ [PF6]- and related compounds |
| |
Authors: | Brian E. Mann Alfredo Musco |
| |
Affiliation: | Department of Chemistry, The University, Sheffield S3 7HF, England;C.N.R. Istituto di Chimica delle Macromolecole, Via E. Bassini 15, 20133 Milan, Italy |
| |
Abstract: | The dynamic behaviour of [Pt(/gh3-allyl){P(cyclohexyl)3}2]+[PF6]- has been reinvestigated, and the earlier interpretation of restricted rotation about the Pt—P endorsed. The activation parameters were obtained. [Pt(/gh3-allyl)(PPri3)2]+[PF6]- behaves similarly, while it has not prove possible to stop the rotation in [Pt(/gh3-allyl){P(CH2Ph)3}2]+[PF6]-. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|