Synthesis of 2-substituted hydroquinone derivatives from 1,4-benzoquinone and allyl ethers |
| |
Authors: | Kevin J. Kaurich Paul A. Deck |
| |
Affiliation: | Department of Chemistry, Virginia Tech, Blacksburg, VA, 24061, USA |
| |
Abstract: | B-Alkylpinacolboranes, derived from rhodium-catalyzed hydroboration of allyl ethers with pinacolborane, react with 1,4-benzoquinone under acidic, oxidizing conditions, to afford, after subsequent hydrogenation, 2-substituted hydroquinones in isolated, purified yields of about 50% based on 1,4-benzoquinone. The product hydroquinones have potential use as precursors to poly(arylene ether) and related aromatic polymers. |
| |
Keywords: | Hydroboration Hydroquinone Benzoquinone Wilkinson's catalyst |
本文献已被 ScienceDirect 等数据库收录! |
|