Palladium-catalysed reactions of conjugated enyne oxiranes with organoborons: A diastereoselective method of the synthesis of 2,4,5-trienol derivatives |
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| Authors: | Fırat Ziyanak Melih Kuş Leman Alkan-Karadeniz Levent Artok |
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| Affiliation: | 1. Department of Chemistry, Faculty of Science, Izmir Institute of Technology, Urla, Izmir 35430, Turkey;2. Department of Chemistry, Faculty of Science, Ege University, Bornova, Izmir 35040, Turkey |
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| Abstract: | A palladium-catalysed reaction of conjugated enyne oxiranes with organoboron reagents is described. This method allows aryl-substituted vinylallenes containing a hydroxyl group on the allylic position to be synthesized, with good diastereomeric ratios, under mild conditions. |
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| Keywords: | Allene Vinylallene 2,4,5-Trienol Enyne oxirane Organoboron |
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