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Promoting the Activity of Bifunctional Catalysts for Autoxidation of 1-Octanethiol
引用本文:Jian Hua ZHU*,Zhen WU,Yuan CHUN Department of Chemistry,Nanjing University,Nanjing 210093. Promoting the Activity of Bifunctional Catalysts for Autoxidation of 1-Octanethiol[J]. 中国化学快报, 2001, 0(6)
作者姓名:Jian Hua ZHU*  Zhen WU  Yuan CHUN Department of Chemistry  Nanjing University  Nanjing 210093
作者单位:Jian Hua ZHU*,Zhen WU,Yuan CHUN Department of Chemistry,Nanjing University,Nanjing 210093
基金项目:Chinese Education Ministry
摘    要:Mercaptans in petroleum products wreck the quality of finished products, so it is necessary to remove them in petroleum refining industry. Merox fixed-bed process is widely used in which mercaptans are converted by contacting feedstock with a metal phthalocyanine catalyst in the presence of air and an alkaline agent. However, use of caustic brings a spent caustic disposal problem so that novel caustic-free catalysts are highly desired to meet environment requirements1-3. It is not just simply …


Promoting the Activity of Bifunctional Catalysts for Autoxidation of 1-Octanethiol
Jian Hua ZHU,Zhen WU,Yuan CHUN. Promoting the Activity of Bifunctional Catalysts for Autoxidation of 1-Octanethiol[J]. Chinese Chemical Letters, 2001, 0(6)
Authors:Jian Hua ZHU  Zhen WU  Yuan CHUN
Affiliation:Jian Hua ZHU*,Zhen WU,Yuan CHUN Department of Chemistry,Nanjing University,Nanjing 210093
Abstract:Methanol and detergent are chosen to be additives for the catalysts derived from active carbon supported MgO and cobalt phthalocyanine (CoPc) or CoPc/NaY zeolite, and dramatically improved the activity and stability of catalyst in autoxidation of 1-octanethiol.
Keywords:Additive   1-octanethiol autoxidation   CoPc/SiO2   CoPc/NaY zeolite.
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