Trapping a pseudo-Hofmann rearrangement on a ruthenium cluster |
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| Authors: | Belletti Daniele Braunstein Pierre Messaoudi Abdelatif Pattacini Roberto Predieri Giovanni Tiripicchio Antonio |
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| Institution: | Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica, Parco Area delle Scienze 17/A, I-43100 Parma, Italy. |
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| Abstract: | In the clusters Ru3(micro(3)-NPPh(3))(micro(3)-OSiMe(3))(micro-X)(micro(C,O)-OCdouble bond]NPPh(3))(micro-CO)(CO)6] (X = NCO, 2; X = Cl, 3), which were prepared by a pyrolytic reaction of Ph(3)PNSiMe(3) with Ru(3)(CO)12, the ligands result from a cluster-mediated pseudo-Hofmann rearrangement involving the micro-NCO, micro(C,O)-Ph(3)Pdouble bond]N-CO and micro(3)-NPPh(3) fragments. |
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