| 浅谈Beckmann重排反应在有机合成中的应用 |
| |
| 引用本文： | 李德江,孙碧海,李斌.浅谈Beckmann重排反应在有机合成中的应用[J].化学教育,2004,25(3):7-9,19. |
| |
| 作者姓名： | 李德江 孙碧海 李斌 |
| |
| 作者单位： | 湖北丹江口市郧阳师范专科学校化学系,442700;武汉化工学院制药工程系,湖北,430073 |
| |
| 摘 要： | 本文讨论了Beckmann重排反应的机理以及酮肟的几何异构、催化剂的选择及溶剂对产物的收率和酰胺异构体比例的影响，并介绍了此重排反应在有机合成上的应用。
|
| 关 键 词： | Beckmann重排反应 机理 酮肟的几何异构 应用 |
The Application of Beckmann Rearrangement Reaction in Organic Synthesis |
| |
| LI Dejiang,SUN Bihai,LI Bin.The Application of Beckmann Rearrangement Reaction in Organic Synthesis[J].Journal of Chemical Education,2004,25(3):7-9,19. |
| |
| Authors: | LI Dejiang SUN Bihai LI Bin |
| |
| Institution: | 1. Department of Chemistry, Yunyang Teachers College, Danjiangkou 442700;2. Department of Engineering, Wuhan Institute of Chemical Technology, Wuhan 430073 |
| |
| Abstract: | In addition to discussing the application and reaction mechanism ofBeckmann rearrangement reaction in organic synthesis, the structure of oxime, the choices of catalysts and solvents having great effects on the yield and the ratio of amide isomers were also reviewed. |
| |
| Keywords: | Beckmann rearrangement reaction mechanism the structure of oxime application |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《化学教育》浏览原始摘要信息 |
| 点击此处可从《化学教育》下载免费的PDF全文 |
