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SYNTHESIS OF POLYMER—SUPPORTED PALLADIUM CATALYSTS AND THEIR CATALYTIC BEHAVIOR FOR THE SELECTIVE HYDROGENATION OF MESITYL OXIDE
作者姓名:LiHong JinXiaonong 等
摘    要:Copolymer of styrene-divinylbenzene in bead from was made by suspension polymerization.After chloromethylation and amination,five kinds of polymeric amines were thus obtained.These polymers were reacted with palladium chloride,and were then reduced.The polymer-supported catalysts synthesized above were used to catalyze the selective hydrogenation of mesityl oxide under reaction conditions of 80℃ and 10kg/cm^2,using methanol as a solvent.The catalytic activity and MIBK(methyl isobutyl ketone) formation selectivity of the catalysts were examined.

关 键 词:合成  钯聚合物  催化行为  选择性氢化作用  异亚丙基丙酮  一缩二丙酮  莱基化氧
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