Stereospecific solid-state NaBH4-promoted reduction of 1-methylpentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione |
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Authors: | Simon G Bott Alan P Marchand Dongxia Xing Rajesh Shukla Stephen James Obrey K Venkatesan J Narasimha Moorthy |
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Institution: | 1. Department of Chemistry, University of North Texas, 76203, Denton, TExas 2. Department of Chemistry, Indian Institute of Science, 560 012, Bangalore, India
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Abstract: | NaBH4 reduction of a cage dione proceeds in a stereospecific fashion to give theendo,endo-diol. This reactivity is related to the crystal structure. |
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