Functionalization of saturated hydrocarbons by aprotic superacids |
| |
| Authors: | I. S. Akhrem I. M. Churilova S. V. Vitt A. V. Orlinkov M. E. Vol'pin |
| |
| Affiliation: | 1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation
|
| |
| Abstract: | The inefficient formylation of adamantane by CO initiated by superacid systems based on polyhalomethanes and aluminum halides becomes selective in the presence of methylcyclopentane and affords 1-adamantanecarbaldehyde in an almost quantitative yield under mild conditions. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
