Functionalization of saturated hydrocarbons by aprotic superacids |
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| Authors: | I S Akhrem I M Churilova S V Vitt A V Orlinkov M E Vol'pin |
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| Institution: | 1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation
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| Abstract: | The inefficient formylation of adamantane by CO initiated by superacid systems based on polyhalomethanes and aluminum halides becomes selective in the presence of methylcyclopentane and affords 1-adamantanecarbaldehyde in an almost quantitative yield under mild conditions. |
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