Kinetics of the reactions of esters and primary amines in “oil-water” type microemulsions |
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| Authors: | A. B. Mirgorodskaya L. A. Kudryavtseva |
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| Affiliation: | 1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083, Kazan', Russian Federation
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| Abstract: | The possibilities of using “oil-water” type microemulsions as a medium for reactions of nucleophilic substitution in esters have been considered. The kinetics of the reactions ofp-nitrophenyl acetate and caprylate with primary amines in the medium indicated has been studied. The hydrophoby factor, being of great importance for micellar solutions of surfactants, is not substantially manifested in detergent microemulsions: the rate constants of the reactions studied are in fact independent of the length of the alkyl radical of the nucleophile. |
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