| CRYSTAL AND MOLECULAR STRUCTURE OF cis—（μ—PhS—（CH2）3SPh）PdCl2 |
| |
| 引用本文： | 王文珍,姚心侃,等.CRYSTAL AND MOLECULAR STRUCTURE OF cis—（μ—PhS—（CH2）3SPh）PdCl2[J].结构化学,1992,11(1):17-19. |
| |
| 作者姓名： | 王文珍 姚心侃 等 |
| |
| 摘 要： | <正> The title complex, C15S2Cl2H16Pd, Mr = 437. 73, crystallizes in monoclinic space group P21/c with a = 10. 177(2), b=10. 788(1), c= 15. 305(1) (?),β=102. 73(1)°, V = 1638. 1(?)3, Z = 4, Dx =1.77g/cm3, μ = 16.8cm-1, F (000) = 872. The final structure refinement converged with unweighted and weighted R factors of 0. 025 and 0. 033 for 2490 observed unique reflections. The complex has mononuclear structure with the ligand cis-chelated to the Pd(Ⅱ) atom.
|
| 关 键 词： | 晶体结构 分子结构 金属配合物 钯 1 3－二苯硫基丙烷 |
CRYSTAL AND MOLECULAR STRUCTURE OF cis-(μ-PhS-(CH_2)_3SPh)PdCl_2 |
| |
| Institution: | [1]ChemistryDepartment,NankaiUniversity,Tianjin,30007 [2]ChemistryDepartment,NankaiUni |
| |
| Abstract: | The title complex, C15S2Cl2H16Pd, Mr = 437. 73, crystallizes in monoclinic space group P21/c with a = 10. 177(2), b=10. 788(1), c= 15. 305(1) (?),β=102. 73(1)°, V = 1638. 1(?)3, Z = 4, Dx =1.77g/cm3, μ = 16.8cm-1, F (000) = 872. The final structure refinement converged with unweighted and weighted R factors of 0. 025 and 0. 033 for 2490 observed unique reflections. The complex has mononuclear structure with the ligand cis-chelated to the Pd(Ⅱ) atom. |
| |
| Keywords: | |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
