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Blue-light-emitting and hole-transporting molecular materials based on amorphous triphenylamine-functionalized twisted binaphthyl
Authors:Xiao Fan  Zhongping LiDandan Yao  Yuwei ZhangHe Li  Xiaoming LiuYing Mu
Institution:State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, PR China
Abstract:Two stable blue-light-emitting molecular materials containing twisted binaphthyl and peripheral triphenylamine groups were synthesized by Suzuki and Heck cross-coupling reactions. Both compounds exhibit excellent thermal and morphologic stabilities, high glass transition temperatures and good fluorescence quantum yield in films. They serve as both hole-transporting and blue emission materials in organic light-emitting diodes with good external quantum efficiencies.
Keywords:Blue organic light-emitting diodes  Hole-transporting  Amorphous materials  Triphenylamine  Binaphthyl
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