| Synthesis of [MoOS3Cu3I(3, 5-diMePy)4]·CH3CN and (Et4>N)4[Mo4Cu8O4S12{(Ph2PS)2N}4] from Solid State Product [Et< |
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| 作者姓名： | NIUYun-Yin ZHANGQian-Feng XINXin-Quan FUNHoong-Kun |
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| 作者单位： | State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093,State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093,State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093,X-Ray Crystallography Unit, School of Physics, Universiti Sains Malaysia 11800 USM, Penang, Malaysia |
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| 基金项目： | Supported by the National Science Foundation of China(No.29631040). |
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| 摘 要： | Treatment of iodide bridged dimer [NEt4]4[Mo2O2S6Cu6I4Br2] 1 with 3,5-bimethylpyridine or with Kin CH3CN afforded the tetranuclear cluster [MoOS3Cu3I(3,5-diMePy)4]·CH3CN 2 and dodecanuclear cluster (Et4N)4[Mo4Cu8O4S12{(Ph2PS)2N}4] 3. Monomeric 2 possess a nest shaped skeleton. The structure of oligomeric 3 can be regarded as a tetramer of nest shaped MoCu3OS3 groups co polymerized by sharing the limbic Cu atoms.
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| 关 键 词： | 原子簇合物 钼 硫 合成 |
| 收稿时间： | 2001-04-15 |
| 修稿时间： | 2001-05-22 |
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