Hydroperoxidation of alkanes by atmospheric oxygen in the presence of hydroquinone or quinone catalyzed by copper(II) acetate under visible light irradiation |
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| Authors: | G. B. Shulpin and A. N. Druzhinina |
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| Affiliation: | (1) Institute of Chemical Physics, Academy of Sciences, 117977 Moscow, Russia |
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| Abstract: | When a solution of an alkane and hydroquinone (or quinone) in CH3CN irradiated in air by visible light in the presence of catalytic amounts of Cu(OCOCH3)2, the alkyl hydroperoxide is formed.
                     ( ) CH3CN  Cu(OCOCH3)2  .
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