| 水中2,4,6-三芳基-3-芳酰基-4-羟基环己基-1,1-二甲腈的洁净合成 |
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| 引用本文： | 靳通收,尹影,刘利宾,赵莹,李同双. 水中2,4,6-三芳基-3-芳酰基-4-羟基环己基-1,1-二甲腈的洁净合成[J]. 有机化学, 2007, 26(2): 261-265 |
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| 作者姓名： | 靳通收 尹影 刘利宾 赵莹 李同双 |
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| 作者单位： | 河北大学化学与环境科学学院,保定,071002 |
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| 基金项目： | 教育部高等学校青年骨干教师基金和河北省自然科学基金（No、B2006000969）资助项目. |
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| 摘 要： | 研究了十六烷基三乙基溴化铵(HTEAB)催化、水介质中, 查尔酮和丙二腈加热回流合成系列2,4,6-三芳基-3-芳酰基-4-羟基环己基-1,1-二甲腈化合物. 产物经1H NMR, IR和元素分析进行了结构表征. 此方法具有反应条件温和、操作简便、产率较高、环境友好的优点.
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| 关 键 词： | 2,4,6-三芳基-3-芳酰基-4-羟基环己基-1,1-二甲腈 查尔酮 丙二腈 水介质 绿色合成 |
| 收稿时间： | 2006-05-08 |
| 修稿时间： | 2006-05-08 |
Clean Synthesis of 3-Aroyl-2,4,6-triaryl-4-hydroxycyclohexane-1,1-dicarbonitrile in Aqueous Media |
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| JIN Tong-Shou,YIN Ying,LIU Li-Bin,ZHAO Ying,LI Tong-Shuang. Clean Synthesis of 3-Aroyl-2,4,6-triaryl-4-hydroxycyclohexane-1,1-dicarbonitrile in Aqueous Media[J]. Chinese Journal of Organic Chemistry, 2007, 26(2): 261-265 |
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| Authors: | JIN Tong-Shou YIN Ying LIU Li-Bin ZHAO Ying LI Tong-Shuang |
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| Affiliation: | College of Chemistry and Environmental Science, Hebei University, Baoding 071002 |
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| Abstract: | A series of 3-aroyl-2,4,6-triaryl-4-hydroxycyclohexane-1,1-dicarbonitriles were synthesized from chalcones and malononitrile catalyzed by hexadecyltriethyl ammonium bromide (3 mol%) in aqueous media. The structures of all products were characterized by 1H NMR, IR spectra and elemental analysis. This method provides several advantages such as mild conditions, simple work-up procedure, high yields and en- vironment friendliness. In addition, water was chosen as a green solvent. |
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| Keywords: | 3-aroyl-2 4 6-triaryl-4-hydroxycyclohexane-1 1-dicarbonitrile chalcone malononitrile aque- ous media clean synthesis |
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