Preparation of cobalt-tetraphenylporphyrin/reduced graphene oxide nanocomposite and its application on hydrogen peroxide biosensor |
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Authors: | Longzhen Zheng Dan YeLeyan Xiong Jingpeng XuKun Tao Zhijun ZouDanlin Huang Xiaowei KangShaoming Yang Jian Xia |
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Affiliation: | Department of Chemistry and Chemical Engineering, East China Jiao Tong University, Nanchang, Jiangxi 330013, PR China |
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Abstract: | A novel cobalt-tetraphenylporphyrin/reduced graphene oxide (CoTPP/RGO) nanocomposite was prepared by a π–π stacking interaction and characterized by ultraviolet–visible absorption spectroscopy (UV–vis), Fourier transform infrared spectroscopy (FTIR) and electrochemical impedance spectroscopy (EIS). The CoTPP/RGO nanocomposite exhibited high electrocatalytic activity both for oxidation and reduction of H2O2. The current response was linear to H2O2 concentration with the concentration range from 1.0 × 10−7 to 2.4 × 10−3 mol L−1 (R = 0.998) at the reductive potential of −0.20 V and from 1.0 × 10−7 to 4.6 × 10−4 mol L−1 (R = 0.996) at the oxidative potential of +0.50 V. The H2O2 biosensor showed good anti-interfering ability towards oxidative interferences at the oxidative potential of +0.50 V and good anti-interfering ability towards reductive interferences at the reductive potential of −0.20 V. |
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Keywords: | Cobalt-tetraphenylporphyrin Reduced graphene oxide Nanocomposite Hydrogen peroxide biosensor Anti-interfering ability |
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