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Effect of C60 ion sputtering on the compositional depth profiling in XPS for Li(Ni,Co,Mn)O2 electrodes
Authors:Li-Shin Chang
Affiliation:Department of Materials Science and Engineering, National Chung Hsing University, 250, Kuo-Kuang Rd., Taichung 40227, Taiwan, ROC; Instrument Center, National Chung Hsing University, 250, Kuo-Kuang Rd., Taichung 40227, Taiwan, ROC; Material and Chemical Research Laboratories, Industrial Technology Research Institute, 195, Sec. 4, Chung Hsing Rd., Chutung, Hsinchu 31040, Taiwan, ROC
Abstract:The performance of a Li-ion cell strongly depends on the solid-electrolyte interface (SEI) on electrodes. The depth distribution of composition in SEI is normally determined by means of X-ray Photoelectron Spectroscopy (XPS) via Ar ion sputtering. Recently, a new kind of ion gun using C60 ions as sputtering source was introduced. In this report, a comparison between the effects of these two kinds of ion guns on the quantification of Li(Ni,Co,Mn)O2 electrodes was made. It was found that the C60 ion gun is more suitable for analyzing the composition and chemical state of Li(Ni,Co,Mn)O2 electrode since that it causes lower chemical damage in the superficial layer.
Keywords:XPS   Depth profile   Ion sputtering   C60   Li(Ni,Co,Mn)O2
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