Halogen oxidation of mixed aminetungsten tricarbonyls |
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| Authors: | Satish C Tripathi Satish C Srivastava Chandra P Singh |
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| Institution: | (1) Department of Chemistry, University of Gorakhpur, Gorakhpur, U.P., India |
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| Abstract: | Summary Halogen oxidation of mixed aminetungsten tricarbonyls, (L-L.) (amine) (CO)3 W (L-L. =o-phen or 2,2 -bipy; amine = cyclohexylamine, piperidine, morpholine, n-butylamine and n-hexylamine), at ambient temperature resulted in the formation of unusual products (L-L)(amine)(CO)3 W. nX2 (X = 1, n = 1; X = Br, n = 2). Their formation has been inferred on the basis of elemental analysis, i.r. and conductivity measurements. |
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