| Synthesis of Dialkyl-substituted Terminal Olefin |
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| 引用本文： | Shen Yong REN Bao Jian SHEN Qiao Xia GUO. Synthesis of Dialkyl-substituted Terminal Olefin[J]. 中国化学快报, 2005, 16(9): 1213-1216 |
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| 作者姓名： | Shen Yong REN Bao Jian SHEN Qiao Xia GUO |
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| 作者单位： | [1]State Key Laboratory of Heavy Oil Processing, The Key Laboratory of Catalysis of CNPC andFaculty of Chemical Science and Engineering, China University of Petroleum, Beijing 102249 |
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| 基金项目： | Financial support from PetroChina is gratefully acknowledged. |
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| 摘 要： | Dialkyl-substituted terminal olefins were synthesized from the coupling reaction of a-olefins which were catalyzed by zirconocene dichloride/methylalumoxane （MAO） catalyst system under mild condition. High yield was gained and no other oligmer was detected. It was found that the ratio of AI/Zr is responsible for the selectivity of product.
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| 关 键 词： | 二羟基 合成方法 石蜡 耦合反应 催化剂 |
| 收稿时间： | 2004-11-26 |
Synthesis of Dialkyl-substituted Terminal Olefin |
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| Shen;Yong;REN;Bao;Jian;SHEN;Qiao;Xia;GUO. Synthesis of Dialkyl-substituted Terminal Olefin[J]. Chinese Chemical Letters, 2005, 16(9): 1213-1216 |
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| Authors: | Shen Yong REN Bao Jian SHEN Qiao Xia GUO |
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| Abstract: | |
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| Keywords: | Zirconocene dichloride methylalumoxane dialkyl-substituted terminal olefin coupling reaction |
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