Coordination polymers based on aluminum(III) porphyrins |
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Authors: | Davidson Gregory J E Lane Laura A Raithby Paul R Warren John E Robinson Carol V Sanders Jeremy K M |
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Institution: | Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario N9B 3P4, Canada. gjed2@uwindsor.ca |
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Abstract: | Aluminum(III) porphyrin carboxylate complexes have shown an affinity for a sixth nitrogenous ligand. The use of isonicotinic or nicotinic acid, which offers both a carboxylate and a nitrogen donor in the same molecule, resulted in the formation of one-dimensional (1-D) coordination polymers. The complexes and their linear oligomers have been characterized by (1)H NMR spectroscopy and nanoelectrospray ionization spectrometry. X-ray analyses confirmed the formation of the 1-D polymers in the solid state. |
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