A terminal borylene ruthenium complex: from B-H activation to reversible hydrogen release |
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| Authors: | Alcaraz Gilles Helmstedt Ulrike Clot Eric Vendier Laure Sabo-Etienne Sylviane |
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| Affiliation: | Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 04, France. |
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| Abstract: | Starting from RuHCl(H2)(PCy3)2, a terminal ruthenium mesitylborylene complex was obtained via double B-H bond activation of mesitylborane and concomitant release of dihydrogen, such a process being remarkably reversible. |
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