Crystal structures of caesium and rubidium chlorochromates,CsCrO3Cl and RbCrO3Cl |
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Authors: | J J Foster Meta Sterns |
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Institution: | (1) Chemistry Department, School of General Studies, Australian National University, 2600 Canberra, A.C.T., Australia |
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Abstract: | The crystal structures of CsCrO3Cl and RbCrO3Cl have been determined from MoK 1diffractometer data and refined anisotropically toR = 0.029 andR = 0.033 respectively for 769 and 590 statistically significant reflections. CsCrO3Cl, which has a structure of the BaSO4 type, crystallizes in the orthorhombic space groupPnma, witha = 9.928,b = 6.043,c = 8.712 Å andZ = 4. RbCrO3Cl is isostructural with KCrO3C1 and NH4CrO3Cl and crystallizes in the monoclinic space groupP21/c witha = 7.857,b = 7.711,c = 8.055 Å, = 90.43 ° andZ = 4. The geometry of the approximately tetrahedral CrO3Cl– groups is very similar in both structures, and the Cr-Cl and average Cr-O bond distances, corrected for thermal vibration of the terminal atoms, are 2.197 and 1.612 Å in CsCrO3Cl and 2.194 and 1.606 Å in RbCrO3Cl. Caesium ions are in 12-fold coordination and rubidium ions in irregular 11-fold coordination to chlorine and oxygen. |
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