Effective synthesis of cyclic carbonates from carbon dioxide and epoxides by phosphonium iodides as catalysts in alcoholic solvents |
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Authors: | Naoto Aoyagi Yoshio FurushoTakeshi Endo |
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Affiliation: | Molecular Engineering Institute, Kinki University, 11-6 Kayanomori, Iizuka, Fukuoka 820-8555, Japan |
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Abstract: | Phosphonium iodides effectively catalyzed the reaction of CO2 and epoxides under mild conditions such as ordinary pressure and ambient temperature in 2-propanol, and the corresponding five-membered cyclic carbonates were obtained in high yields. |
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Keywords: | Phosphonium iodide Carbon dioxide 2-Propanol Cyclic carbonate Epoxide |
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