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Effective synthesis of cyclic carbonates from carbon dioxide and epoxides by phosphonium iodides as catalysts in alcoholic solvents
Authors:Naoto Aoyagi  Yoshio FurushoTakeshi Endo
Affiliation:Molecular Engineering Institute, Kinki University, 11-6 Kayanomori, Iizuka, Fukuoka 820-8555, Japan
Abstract:Phosphonium iodides effectively catalyzed the reaction of CO2 and epoxides under mild conditions such as ordinary pressure and ambient temperature in 2-propanol, and the corresponding five-membered cyclic carbonates were obtained in high yields.
Keywords:Phosphonium iodide   Carbon dioxide   2-Propanol   Cyclic carbonate   Epoxide
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