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An unusual involvement of NaIO4 in the acetylation of bisphenol during attempted oxidative acetylation
Authors:Deepak Singh  Pradeep T Deota
Institution:Department of Applied Chemistry, Faculty of Technology & Engineering, The Maharaja Sayajirao University of Baroda, Vadodara 390 001, India
Abstract:An unexpected behaviour of compilation of reagent sodium metaperiodate in acetic anhydride for acetylation of bisphenols was observed during attempted oxidative acetylation of bisphenols for the synthesis of a bis-acetoxy cyclohexadienone. The products were characterized by their spectral and analytical data and a probable mechanism for acetylation involving role of NaIO4 is proposed.
Keywords:Bisphenols  Bis-cyclohexadienone  Oxidative acetylation  Acetylation  Bis-triquinane
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