Catalytic fluorination of 1,3-dicarbonyl compounds using iodoarene catalysts |
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| Authors: | Tsugio Kitamura Kazutaka MutaSatoshi Kuriki |
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| Affiliation: | Department of Chemistry and Applied Chemistry, Graduate School of Science and Engineering, Saga University, Honjo-machi, Saga 840-8502, Japan |
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| Abstract: | Catalytic fluorination of 1,3-dicarbonyl compounds with aqueous hydrofluoric acid proceeded efficiently with the aid of iodoarene catalysts in the presence of m-CPBA as a terminal oxidant. o-Iodotoluene, o-iodoanisole, and o-ethyliodobenzene showed a high catalytic efficiency to give 2-fluoro-1,3-dicarbonyl compounds in good yields. |
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| Keywords: | Iodoarene catalysis Fluorination Hydrofluoric acid 1,3-Dicarbonyl compounds |
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