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Selective formation of non-conjugated olefins by samarium(II)-mediated elimination/isomerization of allylic benzoates |
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| Authors: | Sara L. Schaefer,Connor L. RobertsErasmus O. Volz,Monika R. GrassoGregory W. O&rsquo Neil |
| Affiliation: | Department of Chemistry, Western Washington University, Bellingham, WA 98225, USA |
| Abstract: | Aromatic allylic benzoates can be selectively transformed to the corresponding benzoate eliminated olefin by the action of samarium diiodide. Depending on the substrate and the elimination conditions, high selectivity for the non-conjugated alkene product can be achieved. |
| Keywords: | Samarium Elimination Isomerization Non-conjugated |
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