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Environmentally benign deprotection of dithioacetals using 30% hydrogen peroxide catalyzed by Fe(acac)3 and sodium iodide
Authors:Masayuki Kirihara  Satoshi SuzukiYuki Ishizuka  Kento YamazakiRyoji Matsushima  Takaya SuzukiToshiaki Iwai
Affiliation:Department of Materials and Life Science, Shizuoka Institute of Science and Technology, 2200-2 Toyosawa, Fukuroi, Shizuoka 437-8555, Japan
Abstract:The reaction of dithioacetals with 30% hydrogen peroxide in the presence of catalytic amounts of iron(III) acetylacetonate and sodium iodide efficiently produced the corresponding carbonyl compounds in high yields.
Keywords:Deprotection of dithioacetals   Tantalum(V) chloride   Iodide ion   Hydrogen peroxide
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