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SnCl4/Sn catalyzed chemoselective reduction of glycopyranosyl azides for the synthesis of diversely functionalized glycopyranosyl chloroacetamides |
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| Authors: | Laxminarayan Sahoo Anadi Singhamahapatra Katuri JV PaulDuraikkannu Loganathan |
| Institution: | Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India |
| Abstract: | A method for the chemoselective reduction of glycopyranosyl azides using SnCl4 and tin metal as the reducing agent followed by in situ chloroacetylation of the synthesized glycopyranosyl amine was developed. This reaction is applicable to diversely functionalized glycopyranosyl azides for the synthesis of glycopyranosyl chloroacetamides. |
| Keywords: | Glycopyranosyl azide In situ reduction Chloroacetylation Functionalized glycoconjugates |
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