A (3, 4, 14)-connected framework with various distorted triangular magnetic lattices exhibiting field-induced metamagnetism, spin competition and spin reorientation |
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| Authors: | Zhong-Yi Liu Bo Ding En-Cui Yang Xiao-Jun Zhao |
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| Affiliation: | College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin, 300387, P.R. China. |
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| Abstract: | A (3, 4, 14)-connected framework with complicated distorted triangular magnetic lattices, {[Co(7)(H(2)O)(4)(trz)(8)(sip)(2)]·3H(2)O}(n) (trz = 1,2,4-triazolate, sip = 5-sulfoisophthalate), exhibits continuous field-induced metamagnetic transition from an antiferromagnetic ordering to a ferrimagnetic state at 15 kOe, spin competition at 26 kOe and spin reorientation at 50 kOe, respectively. |
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