Highly stereoselective hydroxy-directed Diels-Alder reaction |
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| Authors: | Barriault Louis Thomas Jermaine D O Clément Roxanne |
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| Affiliation: | Department of Chemistry, 10 Marie Curie, University of Ottawa, Ottawa, Canada, K1N 6N5. lbarriau@science.uottawa.ca |
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| Abstract: | The successful stereocontrol of the Diels-Alder reaction of semicyclic dienes possessing a secondary and tertiary allylic magnesium alkoxide alcohol functionality and activated dienophiles such as methyl acrylate, methacrolein, acrolein, and N-phenylmaleimide is described. |
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